The European victors handed over the Champions League trophy in Berlin
Butragueño, Gento and Amancio represented Real Madrid at the ceremony in the city that will host the final on 6 June.
Kroos and James got the other two goals for Real Madrid, who closed out a great week against Celta.
The midfielder reaches this milestone in his second season with the Whites.
In their win in Vigo, the Whites also surpassed the 200 mark in La Liga with the Italian coach at the helm.
In the other semi-final, CSKA meet Olympiacos at 6pm.